A group of researchers led by CSIRO Manufacturing, which is part of Australia's Commonwealth Scientific and Industrial Research Organisation (CSIRO) has utilized a lamination technique known as cold isostatic pressing (CIP) to build a perovskite solar cell that uses a flexible bilayer electrode made of carbon and coated with silver (Ag).
CIP is commonly used to compress different types of powders for the shaping of components and semi-finished parts. It applies an isostatic pressure to a powder sample in all directions and is known for producing high-integrity semi-finished products that show little distortion or cracking when fired.
“CIP involves submerging a sample into a chamber of ambient-temperature fluid, either liquid or gas, which is then isostatically pressurized,” the scientists explained. “The CIP lamination technique is shown to apply very high mechanical pressure (up to 380 MPa) to form a seamless physical connection between the hole transport layer (HTL) and carbon film, without damaging the device, without heat and without the need for additional morphology modifications to the carbon film.”
The 60 µm electrode was coated with a 20 µm silver layer and submerged in a water-filled CIP chamber at the set pressure for 30 s and this process, according to the research group could form a strong bond between the carbon layer and the HTL. “When the CIP pressure was applied, the thickness, morphology and conductivity of the coated electrode films were altered,” it explained. “Following the application of pressure, both films were compressed, with the Ag film reducing to around 16 µm and the carbon film reducing to around 40 µm.”
The academics built the cell with a glass-coated indium tin oxide (ITO) substrate, an electron transport layer (ETL) based on either tin oxide (SnO2), a perovskite absorber, an HTL relying on Spiro-OMeTAD, and the carbon-silver contact.
Tested under standard illumination conditions, the device achieved a power conversion efficiency of 20.8%, an open-circuit voltage of 1.10 V, a short-circuit current density of 23.2 mA/cm2, and a fill factor of 81.3%. These results, the scientists said, are in line with those of reference devices built with more expensive, evaporated gold (Au) electrodes.
“The extreme pressure was combined with the benefits of a coated bilayer electrode consisting of carbon for soft interface contact and silver for high conductivity,” they further explained. “Therefore, performance loss was minimized for large-area carbon perovskite solar cells, with record efficiencies of 19.8% and 16.9% for cell areas of 0.95 cm2 and 5.5 cm2, respectively.”
The novel cell design was introduced in the paper “A high-pressure isostatic lamination technique to fabricate versatile carbon electrode-based perovskite solar cells,” which was recently published in communications materials. “These findings underscore the critical role of interface contact in enhancing carbon perovskite cell performance, and the results pave the way for developing low-cost, efficient, and reliable perovskite solar cells,” the researchers concluded.
Another research group at CSIRO recently claimed record-breaking efficiency when producing fully roll-to-roll printed, flexible solar cells. The researchers said at the time the flexible printed solar cells could be used in industries such as defense, emergency management, construction, agriculture, mining, space exploration and urban infrastructure.
This content is protected by copyright and may not be reused. If you want to cooperate with us and would like to reuse some of our content, please contact: editors@pv-magazine.com.
By submitting this form you agree to pv magazine using your data for the purposes of publishing your comment.
Your personal data will only be disclosed or otherwise transmitted to third parties for the purposes of spam filtering or if this is necessary for technical maintenance of the website. Any other transfer to third parties will not take place unless this is justified on the basis of applicable data protection regulations or if pv magazine is legally obliged to do so.
You may revoke this consent at any time with effect for the future, in which case your personal data will be deleted immediately. Otherwise, your data will be deleted if pv magazine has processed your request or the purpose of data storage is fulfilled.
Further information on data privacy can be found in our Data Protection Policy.